Spinel

IMA-Approved Mineral Species


Properties and Data
Physical Properties
Composition
MgAl2O4
Chemical Name
Magnesium Aluminium Oxide
Molecular Weight
142.264 g/mol
Density
3.6 - 4.1 g/cm3
Mohs Hardness
7.5 - 8
Melting Point
2130 °C (3866 °F - 2403 °K)
Member of
Spinel Subgroup
Crystal System
Isometric
Optical Properties
Type
Isotropic
Refractive Index
n = 1.712 - 1.736
Dispersion Factor
0.026
Additional Information
Spinel is commonly synthesized for use in the gem industry, but serves little use industrially. The extent of commercial use typically comes from Czochralski-grown Cobalt-doped spinel, which is a common Q-Switching crystal.

Currently most spinel is produced via the Verneuil method and is limited to a small range of colors. Most commonly expressed in pale yellows, greens, and blues. It is important to note that all Verneuil spinel is actually a series between MgAl2O4 and Al2O3 (Spinel-Corundum Series). Alumina is supplied to the feedstock to stabilize the resulting crystals. This action is apparently the reason red spinels are not commonly synthesized. Chromium-doped Verneuil spinels are known to crack and break easily. Most spinels commonly form fractures and defects, but chromium worsens it to a degree that makes it unreasonable to grow. What material exists on the market is limited to rare Czochralski spinels doped with chromium.
Variants and Types
Intrinsic
Intrinsic
Color: Colorless
Typical Spinel
Typical Spinel
Color: Red, Pink
Fluorescence: Red
Cause: Chromium Ions
Cobalt Spinel
Cobalt Spinel
Color: Blue, Cyan
Fluorescence: Red (UVA), Cyan (UVC)
Cause: Cobalt Ions
Used for Q-Switchers, Laser Rods
Unnamed Variant
Unnamed Variant
Color: Brown, Yellow, Green
Cause: Iron Ions
Unnamed Variant
Unnamed Variant
Color: Pink
Cause: Research Needed
Production and Synthesis
References
REFERENCES





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