Corundum

IMA-Approved Mineral Species


Properties and Data
Physical Properties
Composition
Al2O3
Chemical Name
Aluminium Oxide
Molecular Weight
101.96 g/mol
Density
3.95 - 4.1 g/cm3
Mohs Hardness
9
Melting Point
2044 °C (3711 °F - 2317 °K)
Member of
Hematite Group
Crystal System
Trigonal
Optical Properties
Type
Uniaxial (-)
Refractive Index
nω = 1.762 - 1.788
nε = 1.759 - 1.763
Dispersion Factor
0.018
Birefringence
δ = 0.008 - 0.009
Additional Information
Otherwise known by Sapphire, Ruby, or Carbuncle

Corundum is an important commodity in the industrial and gemological sectors. This material has a useful combination of unique properties and ease of production. This makes it a common product in the material science market. Its most common use-cases include bearings, plungers, high-temperature ceramics, gauges, high-pressure windows, abrasion-resistant lenses, optical wave guides, semiconductors, and laser excitation media.

Typically, it is most often produced using three methods; Verneuil (Flame Fusion), Czochralski, and Kyropoulos. The Verneuil material makes up the vast majority of synthetic sapphires and rubies on the market. Corundum produced with this method is often clear enough for use in Gemology, which is why it is the preferred source for most of the cut synthetic stones on the market. It does not always produce high quality material, and effectively never approaches optics grade, so it is not preferred where the circumstances require a specific grade of optical purity. Czochralski is more common for use cases such as those. Kyropoulos sapphire is often used for bulk production, though it is not clear where that material tends to go, or how pure it is.

Other methods of production, such a sintering, hydrothermal synthesis, flux synthesis, and others are used, but exist far less as commodities or products for general use.
Variants and Types
Intrinsic
Intrinsic
Color: Colorless
Used for Bearings, Clock Jewels, Specialty Optics
Ruby
Ruby
Color: Red, Pink, Magenta
Fluorescence: Red, Pink (UVC)
Cause: Chromium Ions
Used for Lasers, Bearings, Clock Jewels
Padparadscha
Padparadscha
Color: Purple, Pink, Salmon, Orange
Cause: Iron and Chromium Ions
Typical Sapphire
Typical Sapphire
Color: Blue
Cause: Iron and Titanium Ions
Used for Bearings, Clock Jewels
Unnamed Variant
Unnamed Variant
Color: Green, Yellow, Orange
Cause: Iron Ions
Laser Sapphire
Laser Sapphire
Color: Red, Pink, Orange
Cause: Titanium Ions
Used for Laser Rods, Specialty Optics
Unnamed Variant
Unnamed Variant
Color: Blue, Cyan, Green
Cause: Cobalt Ions
'Alexandrite' Sapphire
'Alexandrite' Sapphire
Color: Purple, Red, Green, Blue, etc
Cause: Vanadium Ions
Effect: Color Change
Star Sapphire / Ruby
Star Sapphire / Ruby
Cause: Rutile (TiO2) Inclusions
Effect: Asterism / Cat's Eye
Production and Synthesis
References
REFERENCES





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